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Abstract The CO-to-H 2 conversion factor ( α CO ) is central to measuring the amount and properties of molecular gas. It is known to vary with environmental conditions, and previous studies have revealed lower α CO in the centers of some barred galaxies on kiloparsec scales. To unveil the physical drivers of such variations, we obtained Atacama Large Millimeter/submillimeter Array bands (3), (6), and (7) observations toward the inner ∼2 kpc of NGC 3627 and NGC 4321 tracing 12 CO, 13 CO, and C 18 O lines on ∼100 pc scales. Our multiline modeling and Bayesian likelihood analysis of these data sets reveal variations of molecular gas density, temperature, optical depth, and velocity dispersion, which are among the key drivers of α CO . The central 300 pc nuclei in both galaxies show strong enhancement of temperature T k ≳ 100 K and density n H 2 > 10 3 cm −3 . Assuming a CO-to-H 2 abundance of 3 × 10 −4 , we derive 4–15 times lower α CO than the Galactic value across our maps, which agrees well with previous kiloparsec-scale measurements. Combining the results with our previous work on NGC 3351, we find a strong correlation of α CO with low- J 12 CO optical depths ( τ CO ), as well as an anticorrelation with T k . The τ CO correlation explains most of the α CO variation in the three galaxy centers, whereas changes in T k influence α CO to second order. Overall, the observed line width and 12 CO/ 13 CO 2–1 line ratio correlate with τ CO variation in these centers, and thus they are useful observational indicators for α CO variation. We also test current simulation-based α CO prescriptions and find a systematic overprediction, which likely originates from the mismatch of gas conditions between our data and the simulations. 

Characterizing the physical conditions at disk scales in class 0 sources is crucial for constraining the protostellar accretion process and the initial conditions for planet formation. We use ALMA 1.3 and 3 mm observations to investigate the physical conditions of the dust around the class 0 binary IRAS 16293–2422 A down to ∼10 au scales. The circumbinary material’s spectral index,α, has a median of 3.1 and a dispersion of ∼0.2, providing no firm evidence of millimeter-sized grains therein. Continuum substructures with brightness temperature peaks ofT_b∼ 60–80 K at 1.3 mm are observed near the disks at both wavelengths. These peaks do not overlap with strong variations ofα, indicating that they trace high-temperature spots instead of regions with significant optical depth variations. The lower limits to the inferred dust temperature in the hot spots are 122, 87, and 49 K. Depending on the assumed dust opacity index, these values can be several times higher. They overlap with high gas temperatures and enhanced complex organic molecular emission. This newly resolved dust temperature distribution is in better agreement with the expectations from mechanical instead of the most commonly assumed radiative heating. In particular, we find that the temperatures agree with shock heating predictions. This evidence and recent studies highlighting accretion heating in class 0 disks suggest that mechanical heating (shocks, dissipation powered by accretion, etc.) is important during the early stages and should be considered when modeling and measuring properties of deeply embedded protostars and disks.

 

We compare observations of Hifrom the Very Large Array (VLA) and the Arecibo Observatory and observations of HCO⁺from the Atacama Large Millimeter/submillimeter Array (ALMA) and the Northern Extended Millimeter Array (NOEMA) in the diffuse (A_V≲ 1) interstellar medium (ISM) to predictions from a photodissociation region (PDR) chemical model and multiphase ISM simulations. Using a coarse grid of PDR models, we estimate the density, FUV radiation field, and cosmic-ray ionization rate (CRIR) for each structure identified in HCO⁺and Hiabsorption. These structures fall into two categories. Structures withT_s< 40 K, mostly withN(HCO⁺) ≲ 10¹²cm⁻², are consistent with modest density, FUV radiation field, and CRIR models, typical of the diffuse molecular ISM. Structures with spin temperatureT_s> 40 K, mostly withN(HCO⁺) ≳ 10¹²cm⁻², are consistent with high density, FUV radiation field, and CRIR models, characteristic of environments close to massive star formation. The latter are also found in directions with a significant fraction of thermally unstable Hi. In at least one case, we rule out the PDR model parameters, suggesting that alternative mechanisms (e.g., nonequilibrium processes like turbulent dissipation and/or shocks) are required to explain the observed HCO⁺in this direction. Similarly, while our observations and simulations of the turbulent, multiphase ISM agree that HCO⁺formation occurs along sight lines withN(H I) ≳ 10²¹cm⁻², the simulated data fail to explain HCO⁺column densities ≳ few × 10¹²cm⁻². Because a majority of our sight lines with HCO⁺had such high column densities, this likely indicates that nonequilibrium chemistry is important for these lines of sight.

 

We have complemented existing observations of Hiabsorption with new observations of HCO⁺, C₂H, HCN, and HNC absorption from the Atacama Large Millimeter/submillimeter Array and the Northern Extended Millimeter Array in the directions of 20 background radio continuum sources with 4° ≤ ∣b∣ ≤ 81° to constrain the atomic gas conditions that are suitable for the formation of diffuse molecular gas. We find that these molecular species form along sightlines whereA_V≳ 0.25, consistent with the threshold for the Hi-to-H₂transition at solar metallicity. Moreover, we find that molecular gas is associated only with structures that have an Hioptical depth >0.1, a spin temperature <80 K, and a turbulent Mach number ≳ 2. We also identify a broad, faint component to the HCO⁺absorption in a majority of sightlines. Compared to the velocities where strong, narrow HCO⁺absorption is observed, the Hiat these velocities has a lower cold neutral medium fraction and negligible CO emission. The relative column densities and linewidths of the different molecular species observed here are similar to those observed in previous experiments over a range of Galactic latitudes, suggesting that gas in the solar neighborhood and gas in the Galactic plane are chemically similar. For a select sample of previously observed sightlines, we show that the absorption line profiles of HCO⁺, HCN, HNC, and C₂H are stable over periods of ∼3 yr and ∼25 yr, likely indicating that molecular gas structures in these directions are at least ≳100 au in size.